RUcore Resource Object
RUcore Resource Object
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TitleSpirodiepoxide application
NameKiren, Sezgin (author), Williams, Lawrence (chair), Knapp, Spencer (internal member), LaVoie, Edmond (outside member), Rutgers University, Graduate School - New Brunswick,
Degree Date2008-10
Date Created2008
SubjectChemistry,
Organic compounds--Synthesis
DescriptionThe complete structure of Psymberin was determined with the application of the Universal NMR database approach. A formal synthesis of psymberin was completed with the application of spirodiepoxides. An assembly of a dihydroisocumarin ring was accomplished from a complex aldehyde and an anion derived from a pentasubstituted arene. A new condition to couple an aldehyde and an amide was achieved to reach a carbinolamide moiety. This condition was applied for the synthesis of analogs and hybrid structures. In a separate study, a metal and a ligand were investigated to promote the coupling between thioacids and azides.
NotePh.D.
NoteIncludes bibliographical references
Noteby Sezgin Kiren
Genretheses
Persistent URLhttp://hdl.rutgers.edu/1782.2/rucore10001600001.ETD.000051967
Languageeng
CollectionGraduate School - New Brunswick Electronic Theses and Dissertations
Organization NameRutgers, The State University of New Jersey
RightsThe author owns the copyright to this work
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